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Frontiers | Toxicity of metal-based nanoparticles: Challenges in the nano era

The study was further extended by synthesizing a series of ( E )-2-((substitutedphenyl)diazenyl)phenyl-4-methylbenzenesulfonate ( 12a – b ) and (E)-2-((substituted phenyl)diazenyl)phenol derivatives ( 12c – d ) (Figure 6) and most of the compounds were strongly inhibit the tyrosinase in a dose-dependent manner

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But suffice it to say the compound rapamycin was identified first long before a really amazing guy named David Sabatini as a PhD student at Hopkins in 1993, 1994 as a side project in a lab made the discovery that this thing, rapamycin, was actually working by inhibiting a protein complex of which TOR, target of rapamycin, as it became named was the central piece